David Blaine (born 1973), American illusionist and stunt performer
Hal Blaine (born 1929), one of the most prolific drummers in pop music history
James G. Blaine (1830–1893), a Speaker of the United States House of Representatives, after whom are named Blaine Amendments, which forbid direct government aid to educational institutions that have any religious affiliation
John J. Blaine (1875–1934), United States Senator and governor of Wisconsin
Blaine the Mono, a psychotic artificial intelligence-controlled monorail locomotive in Stephen King's novels The Wastelands and Wizard and Glass (adjoining books in his Dark Tower series)
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